TY - JOUR

T1 - Time scales for transitions between free-energy minima of a dense hard-sphere system

AU - Dasgupta, Chandan

AU - Valls, Oriol T.

N1 - Copyright:
Copyright 2017 Elsevier B.V., All rights reserved.

PY - 1996

Y1 - 1996

N2 - Time scales associated with activated transitions between glassy metastable states of a free-energy functional appropriate for a dense hard-sphere system are calculated by using a new Monte Carlo method for the local density variables. In particular, we calculate the time the system, initially placed in a shallow glassy minimum of the free energy, spends in the neighborhood of this minimum before making a transition to the basin of attraction of another free-energy minimum. This time scale is found to increase as the average density is increased. We find a crossover density near which this time scale increases very sharply and becomes longer than the longest times accessible in our simulation. This time scale does not show any evidence of increasing with sample size.

AB - Time scales associated with activated transitions between glassy metastable states of a free-energy functional appropriate for a dense hard-sphere system are calculated by using a new Monte Carlo method for the local density variables. In particular, we calculate the time the system, initially placed in a shallow glassy minimum of the free energy, spends in the neighborhood of this minimum before making a transition to the basin of attraction of another free-energy minimum. This time scale is found to increase as the average density is increased. We find a crossover density near which this time scale increases very sharply and becomes longer than the longest times accessible in our simulation. This time scale does not show any evidence of increasing with sample size.

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U2 - 10.1103/PhysRevE.53.2603

DO - 10.1103/PhysRevE.53.2603

M3 - Article

AN - SCOPUS:0000319550

VL - 53

SP - 2603

EP - 2612

JO - Physical Review E - Statistical, Nonlinear, and Soft Matter Physics

JF - Physical Review E - Statistical, Nonlinear, and Soft Matter Physics

SN - 1539-3755

IS - 3

ER -