TY - JOUR
T1 - Tris(η4‐naphthalene)zirconate(2−)
AU - Jang, Meehae
AU - Ellis, John E.
PY - 1994/10/17
Y1 - 1994/10/17
N2 - Highly reactive, thermally stable, and air sensitive are three characteristics of the dark red title compound 1, which was prepared from ZrCl4·2 THF and potassium naphthalenide. The three naphthalene ligands are bound η4 to the Zr center and the co‐ordination environment has approximate C3v, local symmetry (shown on the right). Compound 1 is the first tris(naphthalene) complex and the first structurally characterized homoleptic naphthalene metalate. (Figure Presented.)
AB - Highly reactive, thermally stable, and air sensitive are three characteristics of the dark red title compound 1, which was prepared from ZrCl4·2 THF and potassium naphthalenide. The three naphthalene ligands are bound η4 to the Zr center and the co‐ordination environment has approximate C3v, local symmetry (shown on the right). Compound 1 is the first tris(naphthalene) complex and the first structurally characterized homoleptic naphthalene metalate. (Figure Presented.)
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U2 - 10.1002/anie.199419731
DO - 10.1002/anie.199419731
M3 - Article
AN - SCOPUS:33745158975
SN - 0570-0833
VL - 33
SP - 1973
EP - 1975
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 19
ER -