Unexpected fluorescence properties in an axially σ-bonded ferrocenyl-containing porphyrin

Pavlo V. Solntsev; Jared R. Sabin; Samantha J. Dammer; Nikolay N. Gerasimchuk; Victor N. Nemykin

doi:10.1039/c0cc02171g

Unexpected fluorescence properties in an axially σ-bonded ferrocenyl-containing porphyrin

Pavlo V. Solntsev, Jared R. Sabin, Samantha J. Dammer, Nikolay N. Gerasimchuk, Victor N. Nemykin

Chemistry (Twin Cities)

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Abstract

Molecular structure, redox, and unexpected fluorescence properties of a tetraphenylporphyrin tin(iv) complex axially σ-bonded with two ferrocene substituents were investigated using UV-vis, MCD, electro- and spectroelectrochemical methods as well as DFT calculations and X-ray crystallography.

Original language	English (US)
Pages (from-to)	6581-6583
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	35
DOIs	https://doi.org/10.1039/c0cc02171g
State	Published - Sep 21 2010

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abstract = "Molecular structure, redox, and unexpected fluorescence properties of a tetraphenylporphyrin tin(iv) complex axially σ-bonded with two ferrocene substituents were investigated using UV-vis, MCD, electro- and spectroelectrochemical methods as well as DFT calculations and X-ray crystallography.",

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AU - Solntsev, Pavlo V.

AU - Sabin, Jared R.

AU - Dammer, Samantha J.

AU - Gerasimchuk, Nikolay N.

AU - Nemykin, Victor N.

PY - 2010/9/21

Y1 - 2010/9/21

N2 - Molecular structure, redox, and unexpected fluorescence properties of a tetraphenylporphyrin tin(iv) complex axially σ-bonded with two ferrocene substituents were investigated using UV-vis, MCD, electro- and spectroelectrochemical methods as well as DFT calculations and X-ray crystallography.

AB - Molecular structure, redox, and unexpected fluorescence properties of a tetraphenylporphyrin tin(iv) complex axially σ-bonded with two ferrocene substituents were investigated using UV-vis, MCD, electro- and spectroelectrochemical methods as well as DFT calculations and X-ray crystallography.

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Unexpected fluorescence properties in an axially σ-bonded ferrocenyl-containing porphyrin

Abstract

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