UNIAXIAL DEFORMATION OF RUBBER NETWORK CHAINS BY SMALL ANGLE NEUTRON SCATTERING.

Hyuk Yu; Toshiaki Kitano; Chung Yap Kim; Eric J. Amis; Taihyun Chang; Michael R. Landry; Jeffrey A. Wesson; Charles C. Han; Timothy P. Lodge; Charles J. Glinka

UNIAXIAL DEFORMATION OF RUBBER NETWORK CHAINS BY SMALL ANGLE NEUTRON SCATTERING.

Hyuk Yu, Toshiaki Kitano, Chung Yap Kim, Eric J. Amis, Taihyun Chang, Michael R. Landry, Jeffrey A. Wesson, Charles C. Han, Timothy P. Lodge, Charles J. Glinka

Chemistry (Twin Cities)

Research output: Contribution to journal › Conference article › peer-review

3 Scopus citations

Abstract

Rubber elasticity of a polymer network is one of the most distinctive features of a long chain molecule. The retractive force of such a network is mainly due to the change of configurational entropy of network strands. The authors have prepared alpha , omega -dihydroxypoly(isoprene) prepolymers by anionic method and crosslinked them with a trifunctional reagent to form network. With higher molecular weights of the prepolymers than hitherto tried, we were able to stretch the sample up to a factor of two in extension ratio and the scattering from deuterated network strands in 8% and 15% by weight was precise enough to afford quantitative comparison with the theories.

Original language	English (US)
Pages (from-to)	60-61
Number of pages	2
Journal	American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume	26
Issue number	2
State	Published - Sep 1985

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title = "UNIAXIAL DEFORMATION OF RUBBER NETWORK CHAINS BY SMALL ANGLE NEUTRON SCATTERING.",

abstract = "Rubber elasticity of a polymer network is one of the most distinctive features of a long chain molecule. The retractive force of such a network is mainly due to the change of configurational entropy of network strands. The authors have prepared alpha , omega -dihydroxypoly(isoprene) prepolymers by anionic method and crosslinked them with a trifunctional reagent to form network. With higher molecular weights of the prepolymers than hitherto tried, we were able to stretch the sample up to a factor of two in extension ratio and the scattering from deuterated network strands in 8% and 15% by weight was precise enough to afford quantitative comparison with the theories.",

author = "Hyuk Yu and Toshiaki Kitano and Kim, {Chung Yap} and Amis, {Eric J.} and Taihyun Chang and Landry, {Michael R.} and Wesson, {Jeffrey A.} and Han, {Charles C.} and Lodge, {Timothy P.} and Glinka, {Charles J.}",

year = "1985",

month = sep,

language = "English (US)",

volume = "26",

pages = "60--61",

journal = "American Chemical Society, Polymer Preprints, Division of Polymer Chemistry",

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T1 - UNIAXIAL DEFORMATION OF RUBBER NETWORK CHAINS BY SMALL ANGLE NEUTRON SCATTERING.

AU - Yu, Hyuk

AU - Kitano, Toshiaki

AU - Kim, Chung Yap

AU - Amis, Eric J.

AU - Chang, Taihyun

AU - Landry, Michael R.

AU - Wesson, Jeffrey A.

AU - Han, Charles C.

AU - Lodge, Timothy P.

AU - Glinka, Charles J.

PY - 1985/9

Y1 - 1985/9

N2 - Rubber elasticity of a polymer network is one of the most distinctive features of a long chain molecule. The retractive force of such a network is mainly due to the change of configurational entropy of network strands. The authors have prepared alpha , omega -dihydroxypoly(isoprene) prepolymers by anionic method and crosslinked them with a trifunctional reagent to form network. With higher molecular weights of the prepolymers than hitherto tried, we were able to stretch the sample up to a factor of two in extension ratio and the scattering from deuterated network strands in 8% and 15% by weight was precise enough to afford quantitative comparison with the theories.

AB - Rubber elasticity of a polymer network is one of the most distinctive features of a long chain molecule. The retractive force of such a network is mainly due to the change of configurational entropy of network strands. The authors have prepared alpha , omega -dihydroxypoly(isoprene) prepolymers by anionic method and crosslinked them with a trifunctional reagent to form network. With higher molecular weights of the prepolymers than hitherto tried, we were able to stretch the sample up to a factor of two in extension ratio and the scattering from deuterated network strands in 8% and 15% by weight was precise enough to afford quantitative comparison with the theories.

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M3 - Conference article

AN - SCOPUS:0022122355

SN - 0032-3934

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JF - American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

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ER -

UNIAXIAL DEFORMATION OF RUBBER NETWORK CHAINS BY SMALL ANGLE NEUTRON SCATTERING.

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