Viscoelasticity of tightly entangled solutions of semiflexible polymers

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Abstract

A molecular model is introduced to describe the linear viscoelasticity of tightly entangled solutions of semiflexible polymers. An expression for the stress of a solution of wormlike chains is derived, and a tube model is used to describe the effects of entanglement. Consideration of the Brownian dynamics of the polymer within its tube yields a dynamic modulus [Formula Presented] at high frequencies, in agreement with the results of recent microrheology experiments on actin solutions.

Original languageEnglish (US)
Pages (from-to)R1237-R1240
JournalPhysical Review E - Statistical Physics, Plasmas, Fluids, and Related Interdisciplinary Topics
Volume58
Issue number2
DOIs
StatePublished - 1998

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