Analyte-additive interactions in nonaqueous capillary electrophoresis: A critical review

Michael T. Bowser; Andrea R. Kranack; David D.Y. Chen

doi:10.1016/S0165-9936(98)00032-6

Analyte-additive interactions in nonaqueous capillary electrophoresis: A critical review

Michael T. Bowser, Andrea R. Kranack, David D.Y. Chen

Chemistry (Twin Cities)

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78 Scopus citations

Abstract

This article reviews the recent developments in nonaqueous capillary electrophoresis and discusses the effect of the solvent on analyte-additive interactions. When nonaqueous solvents are used, solvophobic interactions are generally weaker than those in water; therefore, those additives that can change the analyte mobility through electrostatic or donor-acceptor interactions should be further explored.

Original language	English (US)
Pages (from-to)	424-434
Number of pages	11
Journal	TrAC - Trends in Analytical Chemistry
Volume	17
Issue number	7
DOIs	https://doi.org/10.1016/S0165-9936(98)00032-6
State	Published - Aug 1998

Keywords

Cohesion energy density
Dielectric constant
Electron donor-acceptor interaction
Nonaqueous capillary electrophoresis
Solvent effect

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KW - Solvent effect

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Analyte-additive interactions in nonaqueous capillary electrophoresis: A critical review

Abstract

Keywords

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