Application of 29Si and 27Al NMR to determine the distribution of anions in sodium silicate and sodium alumino-silicate solutions

A. V. McCormick; A. T. Bell; C. J. Radke

doi:10.1016/S0167-2991(09)60880-6

Application of ²⁹Si and ²⁷Al NMR to determine the distribution of anions in sodium silicate and sodium alumino-silicate solutions

A. V. McCormick, A. T. Bell, C. J. Radke

Chemical Engineering and Materials Science

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

Quantitative ²⁹Si FT-NMR spectra of sodium silicate solutions was used to characterize the distribution of soluble silicate species as a function of solution composition. Silica, alumina, and soda concentrations were employed that are characteristic of those used for zeolite synthesis [1-3 mol% SiO₂; SiO₂/Na₂O = 1-3; 0-0.5 mol% Al ₂O₃]. Silicate structures containing one to twelve Si atoms have been identified. The concentration of these species is a strong function of silicate ratio and can be maximized by adjusting that ratio. Aluminate ions readily react with silicate ions to form new structures containing one or two Si atoms bonded to one Al atom.

Original language	English (US)
Pages (from-to)	247-254
Number of pages	8
Journal	Studies in Surface Science and Catalysis
Volume	28
Issue number	C
DOIs	https://doi.org/10.1016/S0167-2991(09)60880-6
State	Published - 1986

Bibliographical note

Funding Information:
This work was supported by the Office of Basic Energy Sciences, Material Sciences Division of the U.S. Department of Energy under Contract DE-AC03-76SF00098. Fellowship support for Alon V. McCormick was provided by the National Science Foundation.

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title = "Application of 29Si and 27Al NMR to determine the distribution of anions in sodium silicate and sodium alumino-silicate solutions",

abstract = "Quantitative 29Si FT-NMR spectra of sodium silicate solutions was used to characterize the distribution of soluble silicate species as a function of solution composition. Silica, alumina, and soda concentrations were employed that are characteristic of those used for zeolite synthesis [1-3 mol% SiO2; SiO2/Na2O = 1-3; 0-0.5 mol% Al 2O3]. Silicate structures containing one to twelve Si atoms have been identified. The concentration of these species is a strong function of silicate ratio and can be maximized by adjusting that ratio. Aluminate ions readily react with silicate ions to form new structures containing one or two Si atoms bonded to one Al atom.",

author = "McCormick, {A. V.} and Bell, {A. T.} and Radke, {C. J.}",

note = "Funding Information: This work was supported by the Office of Basic Energy Sciences, Material Sciences Division of the U.S. Department of Energy under Contract DE-AC03-76SF00098. Fellowship support for Alon V. McCormick was provided by the National Science Foundation.",

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AU - McCormick, A. V.

AU - Bell, A. T.

AU - Radke, C. J.

N1 - Funding Information: This work was supported by the Office of Basic Energy Sciences, Material Sciences Division of the U.S. Department of Energy under Contract DE-AC03-76SF00098. Fellowship support for Alon V. McCormick was provided by the National Science Foundation.

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N2 - Quantitative 29Si FT-NMR spectra of sodium silicate solutions was used to characterize the distribution of soluble silicate species as a function of solution composition. Silica, alumina, and soda concentrations were employed that are characteristic of those used for zeolite synthesis [1-3 mol% SiO2; SiO2/Na2O = 1-3; 0-0.5 mol% Al 2O3]. Silicate structures containing one to twelve Si atoms have been identified. The concentration of these species is a strong function of silicate ratio and can be maximized by adjusting that ratio. Aluminate ions readily react with silicate ions to form new structures containing one or two Si atoms bonded to one Al atom.

AB - Quantitative 29Si FT-NMR spectra of sodium silicate solutions was used to characterize the distribution of soluble silicate species as a function of solution composition. Silica, alumina, and soda concentrations were employed that are characteristic of those used for zeolite synthesis [1-3 mol% SiO2; SiO2/Na2O = 1-3; 0-0.5 mol% Al 2O3]. Silicate structures containing one to twelve Si atoms have been identified. The concentration of these species is a strong function of silicate ratio and can be maximized by adjusting that ratio. Aluminate ions readily react with silicate ions to form new structures containing one or two Si atoms bonded to one Al atom.

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