Asymmetric synthesis of umuravumbolide1

M. Venkat Ram Reddy; John P. Rearick; Nyssa Hoch; P. Veeraraghavan Ramachandran

doi:10.1021/ol006583z

Asymmetric synthesis of umuravumbolide1

M. Venkat Ram Reddy, John P. Rearick, Nyssa Hoch, P. Veeraraghavan Ramachandran

Chemistry & Biochemistry

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Abstract

(equation presented) This first asymmetric synthesis of enantiopure desacetylumuravumbolide and umuravumbolide via asymmetric reduction, allylboration, and ring-closing metathesis confirms their revised structures and configurations. A convenient procedure to upgrade the enantiopurity of α,β-acetylenic alcohols is also described.

Original language	English (US)
Pages (from-to)	19-20
Number of pages	2
Journal	Organic Letters
Volume	3
Issue number	1
DOIs	https://doi.org/10.1021/ol006583z
State	Published - Jan 11 2001

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title = "Asymmetric synthesis of umuravumbolide1",

abstract = "(equation presented) This first asymmetric synthesis of enantiopure desacetylumuravumbolide and umuravumbolide via asymmetric reduction, allylboration, and ring-closing metathesis confirms their revised structures and configurations. A convenient procedure to upgrade the enantiopurity of α,β-acetylenic alcohols is also described.",

author = "{Venkat Ram Reddy}, M. and Rearick, {John P.} and Nyssa Hoch and {Veeraraghavan Ramachandran}, P.",

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T1 - Asymmetric synthesis of umuravumbolide1

AU - Venkat Ram Reddy, M.

AU - Rearick, John P.

AU - Hoch, Nyssa

AU - Veeraraghavan Ramachandran, P.

PY - 2001/1/11

Y1 - 2001/1/11

N2 - (equation presented) This first asymmetric synthesis of enantiopure desacetylumuravumbolide and umuravumbolide via asymmetric reduction, allylboration, and ring-closing metathesis confirms their revised structures and configurations. A convenient procedure to upgrade the enantiopurity of α,β-acetylenic alcohols is also described.

AB - (equation presented) This first asymmetric synthesis of enantiopure desacetylumuravumbolide and umuravumbolide via asymmetric reduction, allylboration, and ring-closing metathesis confirms their revised structures and configurations. A convenient procedure to upgrade the enantiopurity of α,β-acetylenic alcohols is also described.

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Asymmetric synthesis of umuravumbolide1

Abstract

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