Competitive binding of fluorosulfate anion in reactions of halogens and nitronium borofluoride with olefins

N. S. Zefirov; A. S. Koz'min; V. D. Sorokin; V. V. Zhdankin; Yu N. Studnev; A. V. Fokin

doi:10.1007/BF00951286

Competitive binding of fluorosulfate anion in reactions of halogens and nitronium borofluoride with olefins

N. S. Zefirov, A. S. Koz'min, V. D. Sorokin, V. V. Zhdankin, Yu N. Studnev, A. V. Fokin

Chemistry & Biochemistry

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Abstract

Reactions of olefins with chlorine in the presence of fluorosulfonic acid salts lead to β-chloroalkyl fluorosulfates together with 1,2-dichlorides. The addition of nitronium borofluoride to ethylene in the presence of tetraethylammonium fluorosulfate gives 2-nitroethyl fluorosulfate. These reactions confirm the general character of the competitive binding of superweak nucleophiles in Ad_E reactions.

Original language	English (US)
Pages (from-to)	356-358
Number of pages	3
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	34
Issue number	2
DOIs	https://doi.org/10.1007/BF00951286
State	Published - Feb 1985

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title = "Competitive binding of fluorosulfate anion in reactions of halogens and nitronium borofluoride with olefins",

abstract = "Reactions of olefins with chlorine in the presence of fluorosulfonic acid salts lead to β-chloroalkyl fluorosulfates together with 1,2-dichlorides. The addition of nitronium borofluoride to ethylene in the presence of tetraethylammonium fluorosulfate gives 2-nitroethyl fluorosulfate. These reactions confirm the general character of the competitive binding of superweak nucleophiles in AdE reactions.",

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year = "1985",

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doi = "10.1007/BF00951286",

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pages = "356--358",

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T1 - Competitive binding of fluorosulfate anion in reactions of halogens and nitronium borofluoride with olefins

AU - Zefirov, N. S.

AU - Koz'min, A. S.

AU - Sorokin, V. D.

AU - Zhdankin, V. V.

AU - Studnev, Yu N.

AU - Fokin, A. V.

PY - 1985/2

Y1 - 1985/2

N2 - Reactions of olefins with chlorine in the presence of fluorosulfonic acid salts lead to β-chloroalkyl fluorosulfates together with 1,2-dichlorides. The addition of nitronium borofluoride to ethylene in the presence of tetraethylammonium fluorosulfate gives 2-nitroethyl fluorosulfate. These reactions confirm the general character of the competitive binding of superweak nucleophiles in AdE reactions.

AB - Reactions of olefins with chlorine in the presence of fluorosulfonic acid salts lead to β-chloroalkyl fluorosulfates together with 1,2-dichlorides. The addition of nitronium borofluoride to ethylene in the presence of tetraethylammonium fluorosulfate gives 2-nitroethyl fluorosulfate. These reactions confirm the general character of the competitive binding of superweak nucleophiles in AdE reactions.

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JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

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Competitive binding of fluorosulfate anion in reactions of halogens and nitronium borofluoride with olefins

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