Competitive binding of fluorosulfate anion in reactions of halogens and nitronium borofluoride with olefins

N. S. Zefirov, A. S. Koz'min, V. D. Sorokin, V. V. Zhdankin, Yu N. Studnev, A. V. Fokin

Research output: Contribution to journalArticlepeer-review

Abstract

Reactions of olefins with chlorine in the presence of fluorosulfonic acid salts lead to β-chloroalkyl fluorosulfates together with 1,2-dichlorides. The addition of nitronium borofluoride to ethylene in the presence of tetraethylammonium fluorosulfate gives 2-nitroethyl fluorosulfate. These reactions confirm the general character of the competitive binding of superweak nucleophiles in AdE reactions.

Original languageEnglish (US)
Pages (from-to)356-358
Number of pages3
JournalBulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume34
Issue number2
DOIs
StatePublished - Feb 1 1985

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