Controlled growth of dichlorogermanium oligomers from lewis basic hosts

S. M.Ibrahim Al-Rafia; Mohammad R. Momeni; Robert McDonald; Michael J. Ferguson; Alex Brown; Eric Rivard

doi:10.1002/anie.201302767

Controlled growth of dichlorogermanium oligomers from lewis basic hosts

S. M.Ibrahim Al-Rafia, Mohammad R. Momeni, Robert McDonald, Michael J. Ferguson, Alex Brown, Eric Rivard

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

68 Scopus citations

Abstract

To branch or not to branch: A mild stepwise route to various linear and branched (GeCl₂)_x oligogermylenes supported by Lewis bases is reported, including the carbene-bound Ge₄ complex NHC×GeCl₂Ge(GeCl₃)₂ (see picture). Dipp=2,6-iPr₂C₆H₃, NHC=N-heterocyclic carbene.

Original language	English (US)
Pages (from-to)	6390-6395
Number of pages	6
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	25
DOIs	https://doi.org/10.1002/anie.201302767
State	Published - Jun 17 2013

Keywords

carbenes
density functional calculations
germanium
main group elements
oligomerization

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title = "Controlled growth of dichlorogermanium oligomers from lewis basic hosts",

abstract = "To branch or not to branch: A mild stepwise route to various linear and branched (GeCl2)x oligogermylenes supported by Lewis bases is reported, including the carbene-bound Ge4 complex NHC×GeCl2Ge(GeCl3)2 (see picture). Dipp=2,6-iPr2C6H3, NHC=N-heterocyclic carbene.",

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AU - Brown, Alex

AU - Rivard, Eric

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AB - To branch or not to branch: A mild stepwise route to various linear and branched (GeCl2)x oligogermylenes supported by Lewis bases is reported, including the carbene-bound Ge4 complex NHC×GeCl2Ge(GeCl3)2 (see picture). Dipp=2,6-iPr2C6H3, NHC=N-heterocyclic carbene.

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KW - density functional calculations

KW - germanium

KW - main group elements

KW - oligomerization

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Controlled growth of dichlorogermanium oligomers from lewis basic hosts

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