Dome-distortion and fluorine-lined channels: Synthesis, and molecular and crystal structure of a metal- and C-H bonds-free fluorophthalocyanine

Hyun Jin Lee; William W. Brennessel; Joshua A. Lessing; William W. Brucker; Victor G. Young; Sergiu M. Gorun

doi:10.1039/b303035k

Dome-distortion and fluorine-lined channels: Synthesis, and molecular and crystal structure of a metal- and C-H bonds-free fluorophthalocyanine

Hyun Jin Lee, William W. Brennessel, Joshua A. Lessing, William W. Brucker, Victor G. Young, Sergiu M. Gorun

Chemistry (Twin Cities)

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33 Scopus citations

Abstract

The first perfluorinated metal-free phthalocyanine exhibits a dome-like molecular distortion usually induced by large metal ions. Fluorine-lined channels account for ∼ 39% of the unit cell volume. The intermolecular interlocking of peripheral iso-perfluoroalkyl short-chains contributes to these features, which could be used in the rational design of robust materials.

Original language	English (US)
Pages (from-to)	1576-1577
Number of pages	2
Journal	Chemical Communications
Volume	3
Issue number	13
DOIs	https://doi.org/10.1039/b303035k
State	Published - 2003

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abstract = "The first perfluorinated metal-free phthalocyanine exhibits a dome-like molecular distortion usually induced by large metal ions. Fluorine-lined channels account for ∼ 39% of the unit cell volume. The intermolecular interlocking of peripheral iso-perfluoroalkyl short-chains contributes to these features, which could be used in the rational design of robust materials.",

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AU - Brucker, William W.

AU - Young, Victor G.

AU - Gorun, Sergiu M.

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AB - The first perfluorinated metal-free phthalocyanine exhibits a dome-like molecular distortion usually induced by large metal ions. Fluorine-lined channels account for ∼ 39% of the unit cell volume. The intermolecular interlocking of peripheral iso-perfluoroalkyl short-chains contributes to these features, which could be used in the rational design of robust materials.

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Dome-distortion and fluorine-lined channels: Synthesis, and molecular and crystal structure of a metal- and C-H bonds-free fluorophthalocyanine

Abstract

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