Experimental and theoretical evidence for U(C 6H 6) and Th(C 6H 6) complexes

Ivan Infante; Juraj Raab; Jonathan T. Lyon; Binyong Liang; Lester Andrews; Laura Gagliardi

doi:10.1021/jp076279o

Experimental and theoretical evidence for U(C ₆H ₆) and Th(C ₆H ₆) complexes

Ivan Infante, Juraj Raab, Jonathan T. Lyon, Binyong Liang, Lester Andrews, Laura Gagliardi

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

The vibrational spectra of UBz and ThBz have been measured in solid argon. Complementary quantum chemical calculations have allowed the assignments of the vibrational spectra. According to the calculations, AcBz are stable molecules, as well as other species like BzAcBz and BzAc ₂Bz. Experimentally, there is no evidence for the sandwich compounds BzAcBz and BzAc ₂Bz due to the limitations in the reagent concentrations.

Original language	English (US)
Pages (from-to)	11996-12000
Number of pages	5
Journal	Journal of Physical Chemistry A
Volume	111
Issue number	47
DOIs	https://doi.org/10.1021/jp076279o
State	Published - Nov 29 2007

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title = "Experimental and theoretical evidence for U(C 6H 6) and Th(C 6H 6) complexes",

abstract = "The vibrational spectra of UBz and ThBz have been measured in solid argon. Complementary quantum chemical calculations have allowed the assignments of the vibrational spectra. According to the calculations, AcBz are stable molecules, as well as other species like BzAcBz and BzAc 2Bz. Experimentally, there is no evidence for the sandwich compounds BzAcBz and BzAc 2Bz due to the limitations in the reagent concentrations.",

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AU - Infante, Ivan

AU - Raab, Juraj

AU - Lyon, Jonathan T.

AU - Liang, Binyong

AU - Andrews, Lester

AU - Gagliardi, Laura

PY - 2007/11/29

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AB - The vibrational spectra of UBz and ThBz have been measured in solid argon. Complementary quantum chemical calculations have allowed the assignments of the vibrational spectra. According to the calculations, AcBz are stable molecules, as well as other species like BzAcBz and BzAc 2Bz. Experimentally, there is no evidence for the sandwich compounds BzAcBz and BzAc 2Bz due to the limitations in the reagent concentrations.

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Experimental and theoretical evidence for U(C ₆H ₆) and Th(C ₆H ₆) complexes

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