High-resolution Fourier transform spectrum of HDO in the region 6140-7040 cm-1

O. N. Ulenikov; Shui Ming Hu; E. S. Bekhtereva; G. A. Onopenko; Xiang Huai Wang; Sheng Gui He; Jing Jing Zheng; Qing Shi Zhu

doi:10.1006/jmsp.2001.8382

High-resolution Fourier transform spectrum of HDO in the region 6140-7040 cm^-1

O. N. Ulenikov, Shui Ming Hu, E. S. Bekhtereva, G. A. Onopenko, Xiang Huai Wang, Sheng Gui He, Jing Jing Zheng, Qing Shi Zhu

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

The high-resolution Fourier transform spectrum of the HDO molecule was recorded and analyzed in the region 6140-7040 cm^-1 where the bands v₁ + v₃, 2v₂ + v₃, and 2v₁ + v₂ are located. The presence of strong local resonance interactions allowed us to assign some tens of transitions to the weak bands 5v₂ and v₁ + 3v₂ as well. Spectroscopic parameters of the analyzed bands were estimated. They reproduce initial upper energies with the accuracy close to experimental uncertainties.

Original language	English (US)
Pages (from-to)	224-235
Number of pages	12
Journal	Journal of Molecular Spectroscopy
Volume	208
Issue number	2
DOIs	https://doi.org/10.1006/jmsp.2001.8382
State	Published - 2001

Keywords

HDO molecule
Spectroscopic parameters
Vibration-rotation spectra

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title = "High-resolution Fourier transform spectrum of HDO in the region 6140-7040 cm-1 ",

abstract = "The high-resolution Fourier transform spectrum of the HDO molecule was recorded and analyzed in the region 6140-7040 cm-1 where the bands v1 + v3, 2v2 + v3, and 2v1 + v2 are located. The presence of strong local resonance interactions allowed us to assign some tens of transitions to the weak bands 5v2 and v1 + 3v2 as well. Spectroscopic parameters of the analyzed bands were estimated. They reproduce initial upper energies with the accuracy close to experimental uncertainties.",

keywords = "HDO molecule, Spectroscopic parameters, Vibration-rotation spectra",

author = "Ulenikov, {O. N.} and Hu, {Shui Ming} and Bekhtereva, {E. S.} and Onopenko, {G. A.} and Wang, {Xiang Huai} and He, {Sheng Gui} and Zheng, {Jing Jing} and Zhu, {Qing Shi}",

year = "2001",

doi = "10.1006/jmsp.2001.8382",

language = "English (US)",

volume = "208",

pages = "224--235",

journal = "Journal of Molecular Spectroscopy",

issn = "0022-2852",

publisher = "Academic Press Inc.",

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T1 - High-resolution Fourier transform spectrum of HDO in the region 6140-7040 cm-1

AU - Ulenikov, O. N.

AU - Hu, Shui Ming

AU - Bekhtereva, E. S.

AU - Onopenko, G. A.

AU - Wang, Xiang Huai

AU - He, Sheng Gui

AU - Zheng, Jing Jing

AU - Zhu, Qing Shi

PY - 2001

Y1 - 2001

N2 - The high-resolution Fourier transform spectrum of the HDO molecule was recorded and analyzed in the region 6140-7040 cm-1 where the bands v1 + v3, 2v2 + v3, and 2v1 + v2 are located. The presence of strong local resonance interactions allowed us to assign some tens of transitions to the weak bands 5v2 and v1 + 3v2 as well. Spectroscopic parameters of the analyzed bands were estimated. They reproduce initial upper energies with the accuracy close to experimental uncertainties.

AB - The high-resolution Fourier transform spectrum of the HDO molecule was recorded and analyzed in the region 6140-7040 cm-1 where the bands v1 + v3, 2v2 + v3, and 2v1 + v2 are located. The presence of strong local resonance interactions allowed us to assign some tens of transitions to the weak bands 5v2 and v1 + 3v2 as well. Spectroscopic parameters of the analyzed bands were estimated. They reproduce initial upper energies with the accuracy close to experimental uncertainties.

KW - HDO molecule

KW - Spectroscopic parameters

KW - Vibration-rotation spectra

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DO - 10.1006/jmsp.2001.8382

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JO - Journal of Molecular Spectroscopy

JF - Journal of Molecular Spectroscopy

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