High-resolution Fourier transform spectrum of HDO in the region 6140-7040 cm−1

O. N. Ulenikov; Shui Ming Hu; E. S. Bekhtereva; G. A. Onopenko; Xiang Huai Wang; Sheng Gui He; Jing Jing Zheng; Qing Shi Zhu

doi:10.1006/jmsp.2001.8382

High-resolution Fourier transform spectrum of HDO in the region 6140-7040 cm⁻¹

O. N. Ulenikov, Shui Ming Hu, E. S. Bekhtereva, G. A. Onopenko, Xiang Huai Wang, Sheng Gui He, Jing Jing Zheng, Qing Shi Zhu

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

47 Scopus citations

Abstract

The high-resolution Fourier transform spectrum of the HDO molecule was recorded and analyzed in the region 6140-7040 cm⁻¹ where the bands v₁ + v₃, 2v₂ + v₃, and 2v₁ + v₂ are located. The presence of strong local resonance interactions allowed us to assign some tens of transitions to the weak bands 5v₂ and v₁ + 3v₂ as well. Spectroscopic parameters of the analyzed bands were estimated. They reproduce initial upper energies with the accuracy close to experimental uncertainties.

Original language	English (US)
Pages (from-to)	224-235
Number of pages	12
Journal	Journal of molecular spectroscopy
Volume	208
Issue number	2
DOIs	https://doi.org/10.1006/jmsp.2001.8382
State	Published - 2001

Bibliographical note

Funding Information:
This work was partially supported by the National Project for the Development of Key Fundamental Sciences in China, by the National Natural Science Foundation of China, by the Foundation of the Chinese Academy of Science, and by the Ministry of Education of Russian Federation. O. Ulenikov thanks the University of Science and Technology of China for a guest professorship, and E. Bekhtereva thanks the Ru Jia-xi Foundation for financial support during her stay in Hefei in March–May, 2001.

Keywords

HDO molecule
Spectroscopic parameters
Vibration-rotation spectra

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10.1006/jmsp.2001.8382

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title = "High-resolution Fourier transform spectrum of HDO in the region 6140-7040 cm−1",

abstract = "The high-resolution Fourier transform spectrum of the HDO molecule was recorded and analyzed in the region 6140-7040 cm−1 where the bands v1 + v3, 2v2 + v3, and 2v1 + v2 are located. The presence of strong local resonance interactions allowed us to assign some tens of transitions to the weak bands 5v2 and v1 + 3v2 as well. Spectroscopic parameters of the analyzed bands were estimated. They reproduce initial upper energies with the accuracy close to experimental uncertainties.",

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note = "Funding Information: This work was partially supported by the National Project for the Development of Key Fundamental Sciences in China, by the National Natural Science Foundation of China, by the Foundation of the Chinese Academy of Science, and by the Ministry of Education of Russian Federation. O. Ulenikov thanks the University of Science and Technology of China for a guest professorship, and E. Bekhtereva thanks the Ru Jia-xi Foundation for financial support during her stay in Hefei in March–May, 2001.",

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AU - Ulenikov, O. N.

AU - Hu, Shui Ming

AU - Bekhtereva, E. S.

AU - Onopenko, G. A.

AU - Wang, Xiang Huai

AU - He, Sheng Gui

AU - Zheng, Jing Jing

AU - Zhu, Qing Shi

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PY - 2001

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AB - The high-resolution Fourier transform spectrum of the HDO molecule was recorded and analyzed in the region 6140-7040 cm−1 where the bands v1 + v3, 2v2 + v3, and 2v1 + v2 are located. The presence of strong local resonance interactions allowed us to assign some tens of transitions to the weak bands 5v2 and v1 + 3v2 as well. Spectroscopic parameters of the analyzed bands were estimated. They reproduce initial upper energies with the accuracy close to experimental uncertainties.

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KW - Spectroscopic parameters

KW - Vibration-rotation spectra

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