TY - JOUR
T1 - Highly ordered mesoporous carbon nitride nanoparticles with high nitrogen content
T2 - A metal-free basic catalyst
AU - Jin, Xin
AU - Balasubramanian, Veerappan V.
AU - Selvan, Sakthivel T.
AU - Sawant, Dhanashri P.
AU - Chari, Murugulla A.
AU - Lu, G. Q.
AU - Vinu, Ajayan
PY - 2009/10/5
Y1 - 2009/10/5
N2 - Nitrogen-rich carbon nitride is obtained as ultrasmall, discrete, mesoporous nanoparticles (see picture) by reaction of ethylenediamine with CCl4 in the nanochannels of a mesoporous silica template. Its high nitrogen content, large surface area, and large pore volume make it a highly active catalyst for transesterification of β-keto esters of aryl, aliphatic, and cyclic primary alcohols.
AB - Nitrogen-rich carbon nitride is obtained as ultrasmall, discrete, mesoporous nanoparticles (see picture) by reaction of ethylenediamine with CCl4 in the nanochannels of a mesoporous silica template. Its high nitrogen content, large surface area, and large pore volume make it a highly active catalyst for transesterification of β-keto esters of aryl, aliphatic, and cyclic primary alcohols.
KW - Carbon nitride heterogeneous catalysis mesoporous materials
KW - Nanoparticles
KW - Template synthesis
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U2 - 10.1002/anie.200903674
DO - 10.1002/anie.200903674
M3 - Article
C2 - 19739172
AN - SCOPUS:70349671053
SN - 1433-7851
VL - 48
SP - 7884
EP - 7887
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 42
ER -