IBX amides: A new family of hypervalent iodine reagents

Viktor Zhdankin; Alexey Y. Koposov; Brian C. Netzel; Nikolai V. Yashin; Brian P. Rempel; Michael J. Ferguson; Rik R. Tykwinski

doi:10.1002/anie.200351018

IBX amides: A new family of hypervalent iodine reagents

Viktor Zhdankin, Alexey Y. Koposov, Brian C. Netzel, Nikolai V. Yashin, Brian P. Rempel, Michael J. Ferguson, Rik R. Tykwinski

Chemistry & Biochemistry

Research output: Contribution to journal › Article › peer-review

82 Scopus citations

Abstract

Amides of 2-iodoxybenzoic acid (IBX amides, 1) are a new class of pentavalent iodine compounds with a pseudo-benziodoxole structure. These 2-iodoxybenzamides are useful reagents for the oxidation of alcohols, with a reactivity pattern similar to IBX (R=CH(CH₃)CO₂CH₃ or CH(CH₂Ph)CO₂CH₃ (in crystal structure shown)).

Original language	English (US)
Pages (from-to)	2194-2196
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	42
Issue number	19
DOIs	https://doi.org/10.1002/anie.200351018
State	Published - May 16 2003

Keywords

Alcohols
Hypervalent compounds
Iodine
Oxidation
Synthetic methods

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abstract = "Amides of 2-iodoxybenzoic acid (IBX amides, 1) are a new class of pentavalent iodine compounds with a pseudo-benziodoxole structure. These 2-iodoxybenzamides are useful reagents for the oxidation of alcohols, with a reactivity pattern similar to IBX (R=CH(CH3)CO2CH3 or CH(CH2Ph)CO2CH3 (in crystal structure shown)).",

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AU - Netzel, Brian C.

AU - Yashin, Nikolai V.

AU - Rempel, Brian P.

AU - Ferguson, Michael J.

AU - Tykwinski, Rik R.

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AB - Amides of 2-iodoxybenzoic acid (IBX amides, 1) are a new class of pentavalent iodine compounds with a pseudo-benziodoxole structure. These 2-iodoxybenzamides are useful reagents for the oxidation of alcohols, with a reactivity pattern similar to IBX (R=CH(CH3)CO2CH3 or CH(CH2Ph)CO2CH3 (in crystal structure shown)).

KW - Alcohols

KW - Hypervalent compounds

KW - Iodine

KW - Oxidation

KW - Synthetic methods

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IBX amides: A new family of hypervalent iodine reagents

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