TY - JOUR
T1 - Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmetallen. LXX. Erste Arylrheniumoxide (σ-Aryl)ReO3
AU - Herrmann, Wolfgang A.
AU - Ladwig, Monika
AU - Kiprof, Paul
AU - Riede, Jürgen
PY - 1989/7/18
Y1 - 1989/7/18
N2 - The first examples of arylmetal oxides of general formula (σ-aryl)MOx have been synthesized, for M = Re. The compounds (σ-aryl)ReO3 (3) are obtained in a simple, ostensibly general route by treatment of dirhenium heptoxide with the corresponding arylzinc compound Zn(σ-aryl)2. As side product, the zinc perrhenate Zn(thf)2(ReO4)2 formed and precipitated as insoluble material from the solution. (Mesityltrioxo)rhenium(VII) was characterized by an X-ray diffraction study (pyramidal geometry).
AB - The first examples of arylmetal oxides of general formula (σ-aryl)MOx have been synthesized, for M = Re. The compounds (σ-aryl)ReO3 (3) are obtained in a simple, ostensibly general route by treatment of dirhenium heptoxide with the corresponding arylzinc compound Zn(σ-aryl)2. As side product, the zinc perrhenate Zn(thf)2(ReO4)2 formed and precipitated as insoluble material from the solution. (Mesityltrioxo)rhenium(VII) was characterized by an X-ray diffraction study (pyramidal geometry).
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U2 - 10.1016/0022-328X(89)85218-0
DO - 10.1016/0022-328X(89)85218-0
M3 - Article
AN - SCOPUS:0002029862
SN - 0022-328X
VL - 371
SP - C13-C17
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 1
ER -