Oxidatively Assisted Nucleophilic Substitution of Iodine in Alkyl Iodides by Nucleofugic Anions

Nikolai S. Zefirov, Victor V. Zhdankin, Galina V. Makhon’Kova, Yuri V. Dan’Kov, Anatoly S. Koz’Min

Research output: Contribution to journalArticlepeer-review

32 Scopus citations

Abstract

The reaction of alkyl iodides with chlorine or nitronium tetrafluoroborate in the presence of salts of perchloric or substituted sulfonic acids gave alkyl perchlorates or sulfonates as principal products. Some mechanistic aspects of this new reaction are discussed.

Original languageEnglish (US)
Pages (from-to)1872-1876
Number of pages5
JournalJournal of Organic Chemistry
Volume50
Issue number11
DOIs
StatePublished - May 1985

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