Oxidatively Assisted Nucleophilic Substitution of Iodine in Alkyl Iodides by Nucleofugic Anions

Nikolai S. Zefirov; Victor V. Zhdankin; Galina V. Makhon’Kova; Yuri V. Dan’Kov; Anatoly S. Koz’Min

doi:10.1021/jo00211a017

Oxidatively Assisted Nucleophilic Substitution of Iodine in Alkyl Iodides by Nucleofugic Anions

Nikolai S. Zefirov, Victor V. Zhdankin, Galina V. Makhon’Kova, Yuri V. Dan’Kov, Anatoly S. Koz’Min

Chemistry & Biochemistry

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

The reaction of alkyl iodides with chlorine or nitronium tetrafluoroborate in the presence of salts of perchloric or substituted sulfonic acids gave alkyl perchlorates or sulfonates as principal products. Some mechanistic aspects of this new reaction are discussed.

Original language	English (US)
Pages (from-to)	1872-1876
Number of pages	5
Journal	Journal of Organic Chemistry
Volume	50
Issue number	11
DOIs	https://doi.org/10.1021/jo00211a017
State	Published - May 1985

Access

10.1021/jo00211a017

OpenUrl availability

Full text

Cite this

@article{9903eb9e45064c85bd2918a92c92b41b,

title = "Oxidatively Assisted Nucleophilic Substitution of Iodine in Alkyl Iodides by Nucleofugic Anions",

abstract = "The reaction of alkyl iodides with chlorine or nitronium tetrafluoroborate in the presence of salts of perchloric or substituted sulfonic acids gave alkyl perchlorates or sulfonates as principal products. Some mechanistic aspects of this new reaction are discussed.",

author = "Zefirov, {Nikolai S.} and Zhdankin, {Victor V.} and Makhon{\textquoteright}Kova, {Galina V.} and Dan{\textquoteright}Kov, {Yuri V.} and Koz{\textquoteright}Min, {Anatoly S.}",

year = "1985",

month = may,

doi = "10.1021/jo00211a017",

language = "English (US)",

volume = "50",

pages = "1872--1876",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "11",

}

TY - JOUR

T1 - Oxidatively Assisted Nucleophilic Substitution of Iodine in Alkyl Iodides by Nucleofugic Anions

AU - Zefirov, Nikolai S.

AU - Zhdankin, Victor V.

AU - Makhon’Kova, Galina V.

AU - Dan’Kov, Yuri V.

AU - Koz’Min, Anatoly S.

PY - 1985/5

Y1 - 1985/5

N2 - The reaction of alkyl iodides with chlorine or nitronium tetrafluoroborate in the presence of salts of perchloric or substituted sulfonic acids gave alkyl perchlorates or sulfonates as principal products. Some mechanistic aspects of this new reaction are discussed.

AB - The reaction of alkyl iodides with chlorine or nitronium tetrafluoroborate in the presence of salts of perchloric or substituted sulfonic acids gave alkyl perchlorates or sulfonates as principal products. Some mechanistic aspects of this new reaction are discussed.

UR - http://www.scopus.com/inward/record.url?scp=0004376668&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0004376668&partnerID=8YFLogxK

U2 - 10.1021/jo00211a017

DO - 10.1021/jo00211a017

M3 - Article

AN - SCOPUS:0004376668

SN - 0022-3263

VL - 50

SP - 1872

EP - 1876

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 11

ER -

Oxidatively Assisted Nucleophilic Substitution of Iodine in Alkyl Iodides by Nucleofugic Anions

Abstract

Access

OpenUrl availability

Other files and links

Fingerprint

Cite this