TY - JOUR
T1 - Photovoltaic processes of singlet and triplet excited states in organic solar cells
AU - Xu, Zhihua
AU - Hu, Bin
PY - 2008/9/10
Y1 - 2008/9/10
N2 - This article reports the respective photovoltaic processes of singlet and triplet photoexcited states in dissociation and charge reactions based on the studies of magnetic-field effects of photocurrents. The magnetic-field effects of photocurrents reveal that weak donor-acceptor interactions lead to a two-step photovoltaic process: dissociation in polaron-pair states evolved from singlet excitonic states and exciton-charge reactions occurred in triplet excitonic states in the generation of the photocurrent. However, strong donor-acceptor interactions yield a one-step photovoltaic process: direct dissociation of both singlet and triplet excitons in bulk-heterojunction organic solar cells. In addition, the magnetic-field effects of photocurrents indicate that the dissociated electrons and holes form charge-transfer complexes with singlet and triplet spin configurations at donor-acceptor intermolecular interfaces. As a result, the magnetic-field effects of photocurrents can deliver a critical understanding of singlet and triplet photovoltaic processes to design advanced solar-energy materials and devices.
AB - This article reports the respective photovoltaic processes of singlet and triplet photoexcited states in dissociation and charge reactions based on the studies of magnetic-field effects of photocurrents. The magnetic-field effects of photocurrents reveal that weak donor-acceptor interactions lead to a two-step photovoltaic process: dissociation in polaron-pair states evolved from singlet excitonic states and exciton-charge reactions occurred in triplet excitonic states in the generation of the photocurrent. However, strong donor-acceptor interactions yield a one-step photovoltaic process: direct dissociation of both singlet and triplet excitons in bulk-heterojunction organic solar cells. In addition, the magnetic-field effects of photocurrents indicate that the dissociated electrons and holes form charge-transfer complexes with singlet and triplet spin configurations at donor-acceptor intermolecular interfaces. As a result, the magnetic-field effects of photocurrents can deliver a critical understanding of singlet and triplet photovoltaic processes to design advanced solar-energy materials and devices.
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U2 - 10.1002/adfm.200800331
DO - 10.1002/adfm.200800331
M3 - Article
AN - SCOPUS:52449128999
SN - 1616-301X
VL - 18
SP - 2611
EP - 2617
JO - Advanced Functional Materials
JF - Advanced Functional Materials
IS - 17
ER -