Preparation of [18O]‐chlorocarbonylsulfenyl chloride

Andrew W. Mott; Steven J. Eastep; Urszula Słomczynska; George Barany

doi:10.1002/jlcr.2580210407

Preparation of [¹⁸O]‐chlorocarbonylsulfenyl chloride

Andrew W. Mott, Steven J. Eastep, Urszula Słomczynska, George Barany

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

[¹⁸O]‐Chlorocarbonylsulfenyl chloride with an isotopic purity of 92% was prepared in three steps starting with the [¹⁸O]‐hydrolysis of 2‐ethyl‐1,3‐dioxolane to [¹⁸O]‐propanal, which was then converted to [¹⁸O]‐O‐1‐methylpropyl S‐methyl dithiocarbonate, which was then chlorinated to give the title compound. Distilled yields for the three steps were 57%, 49%, and 40% respectively.

Original language	English (US)
Pages (from-to)	329-336
Number of pages	8
Journal	Journal of Labelled Compounds and Radiopharmaceuticals
Volume	21
Issue number	4
DOIs	https://doi.org/10.1002/jlcr.2580210407
State	Published - Apr 1984

Keywords

[O]‐chlorocarbonylsulfenyl chloride
[O]‐propanal
[O]‐xanthate

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title = "Preparation of [18O]‐chlorocarbonylsulfenyl chloride",

abstract = "[18O]‐Chlorocarbonylsulfenyl chloride with an isotopic purity of 92% was prepared in three steps starting with the [18O]‐hydrolysis of 2‐ethyl‐1,3‐dioxolane to [18O]‐propanal, which was then converted to [18O]‐O‐1‐methylpropyl S‐methyl dithiocarbonate, which was then chlorinated to give the title compound. Distilled yields for the three steps were 57%, 49%, and 40% respectively.",

keywords = "[O]‐chlorocarbonylsulfenyl chloride, [O]‐propanal, [O]‐xanthate",

author = "Mott, {Andrew W.} and Eastep, {Steven J.} and Urszula S{\l}omczynska and George Barany",

year = "1984",

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T1 - Preparation of [18O]‐chlorocarbonylsulfenyl chloride

AU - Mott, Andrew W.

AU - Eastep, Steven J.

AU - Słomczynska, Urszula

AU - Barany, George

PY - 1984/4

Y1 - 1984/4

N2 - [18O]‐Chlorocarbonylsulfenyl chloride with an isotopic purity of 92% was prepared in three steps starting with the [18O]‐hydrolysis of 2‐ethyl‐1,3‐dioxolane to [18O]‐propanal, which was then converted to [18O]‐O‐1‐methylpropyl S‐methyl dithiocarbonate, which was then chlorinated to give the title compound. Distilled yields for the three steps were 57%, 49%, and 40% respectively.

AB - [18O]‐Chlorocarbonylsulfenyl chloride with an isotopic purity of 92% was prepared in three steps starting with the [18O]‐hydrolysis of 2‐ethyl‐1,3‐dioxolane to [18O]‐propanal, which was then converted to [18O]‐O‐1‐methylpropyl S‐methyl dithiocarbonate, which was then chlorinated to give the title compound. Distilled yields for the three steps were 57%, 49%, and 40% respectively.

KW - [O]‐chlorocarbonylsulfenyl chloride

KW - [O]‐propanal

KW - [O]‐xanthate

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JF - Journal of Labelled Compounds and Radiopharmaceuticals

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