RuCl3-catalyzed oxidation of iodoarenes with peracetic acid: New facile preparation of iodylarenes

Alexey Y. Koposov; Rashad R. Karimov; Andrey A. Pronin; Tatyana Skrupskaya; Mekhman S. Yusubov; Viktor Zhdankin

doi:10.1021/jo062073s

RuCl₃-catalyzed oxidation of iodoarenes with peracetic acid: New facile preparation of iodylarenes

Alexey Y. Koposov, Rashad R. Karimov, Andrey A. Pronin, Tatyana Skrupskaya, Mekhman S. Yusubov, Viktor Zhdankin

Chemistry & Biochemistry

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36 Scopus citations

Abstract

New facile methodology for the preparation of pentavalent iodine compounds using peracetic acid as an oxidant in the presence of catalytic amounts of ruthenium trichloride is described. The new procedure allows the preparation of several previously unknown iodylarenes bearing strongly electron-withdrawing CF₃ groups in the aromatic ring.

Original language	English (US)
Pages (from-to)	9912-9914
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	71
Issue number	26
DOIs	https://doi.org/10.1021/jo062073s
State	Published - Dec 22 2006

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title = "RuCl3-catalyzed oxidation of iodoarenes with peracetic acid: New facile preparation of iodylarenes",

abstract = "New facile methodology for the preparation of pentavalent iodine compounds using peracetic acid as an oxidant in the presence of catalytic amounts of ruthenium trichloride is described. The new procedure allows the preparation of several previously unknown iodylarenes bearing strongly electron-withdrawing CF3 groups in the aromatic ring.",

author = "Koposov, {Alexey Y.} and Karimov, {Rashad R.} and Pronin, {Andrey A.} and Tatyana Skrupskaya and Yusubov, {Mekhman S.} and Viktor Zhdankin",

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language = "English (US)",

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T1 - RuCl3-catalyzed oxidation of iodoarenes with peracetic acid

T2 - New facile preparation of iodylarenes

AU - Koposov, Alexey Y.

AU - Karimov, Rashad R.

AU - Pronin, Andrey A.

AU - Skrupskaya, Tatyana

AU - Yusubov, Mekhman S.

AU - Zhdankin, Viktor

PY - 2006/12/22

Y1 - 2006/12/22

N2 - New facile methodology for the preparation of pentavalent iodine compounds using peracetic acid as an oxidant in the presence of catalytic amounts of ruthenium trichloride is described. The new procedure allows the preparation of several previously unknown iodylarenes bearing strongly electron-withdrawing CF3 groups in the aromatic ring.

AB - New facile methodology for the preparation of pentavalent iodine compounds using peracetic acid as an oxidant in the presence of catalytic amounts of ruthenium trichloride is described. The new procedure allows the preparation of several previously unknown iodylarenes bearing strongly electron-withdrawing CF3 groups in the aromatic ring.

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JF - Journal of Organic Chemistry

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ER -

RuCl₃-catalyzed oxidation of iodoarenes with peracetic acid: New facile preparation of iodylarenes

Abstract

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