Abstract
Tin goes in: The solid Lewis acid Sn-zeoliteβ is obtained in a simple and scalable procedure (see scheme). A high metal content can be obtained, without undesirable side-effects. The space-time-yields of the resulting catalysis are over one order-of-magnitude larger than those of the state-of-the-art materials for the Baeyer-Villiger oxidation of cyclohexanone and the synthesis of ethyl lactate from the triose dihydroxyacetone.
Original language | English (US) |
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Pages (from-to) | 11736-11739 |
Number of pages | 4 |
Journal | Angewandte Chemie - International Edition |
Volume | 51 |
Issue number | 47 |
DOIs | |
State | Published - Nov 19 2012 |
Keywords
- Lewis acid catalysis
- selective oxidation
- sustainable chemistry
- triose isomerization
- zeolite synthesis