Sugar anomerism - A short and sweet digression perspective on "the application of ab initio molecular orbital theory to the anomeric effect"

Chris Cramer

doi:10.1007/s002149900068

Sugar anomerism - A short and sweet digression perspective on "the application of ab initio molecular orbital theory to the anomeric effect"

Chris Cramer

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Abstract

The subject paper presented the first conformational analysis of the anomeric effect within the context of molecular orbital theory, discussed the utility of Fourier decomposition of a torsional coordinate as a method for analyzing disparate electronic influences on that coordinate, and helped settle debate on the nature of anomeric stabilization.

Original language	English (US)
Pages (from-to)	308-310
Number of pages	3
Journal	Theoretical Chemistry Accounts
Volume	103
Issue number	3-4
DOIs	https://doi.org/10.1007/s002149900068
State	Published - Feb 2000

Keywords

Carbohydrate
Conformational analysis
Hyperconjugation
Stereoelectronic effects

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AB - The subject paper presented the first conformational analysis of the anomeric effect within the context of molecular orbital theory, discussed the utility of Fourier decomposition of a torsional coordinate as a method for analyzing disparate electronic influences on that coordinate, and helped settle debate on the nature of anomeric stabilization.

KW - Carbohydrate

KW - Conformational analysis

KW - Hyperconjugation

KW - Stereoelectronic effects

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M3 - Review article

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JF - Theoretical Chemistry Accounts

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ER -

Sugar anomerism - A short and sweet digression perspective on "the application of ab initio molecular orbital theory to the anomeric effect"

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