Synthetic Access to Atomically Dispersed Metals in Metal-Organic Frameworks via a Combined Atomic-Layer-Deposition-in-MOF and Metal-Exchange Approach

Rachel C. Klet; Timothy C. Wang; Laura E. Fernandez; Donald G. Truhlar; Joseph T. Hupp; Omar K. Farha

doi:10.1021/acs.chemmater.5b04887

Synthetic Access to Atomically Dispersed Metals in Metal-Organic Frameworks via a Combined Atomic-Layer-Deposition-in-MOF and Metal-Exchange Approach

Rachel C. Klet, Timothy C. Wang, Laura E. Fernandez, Donald G. Truhlar, Joseph T. Hupp, Omar K. Farha

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Abstract

The combination (AIM-ME) of atomic layer deposition in metal-organic frameworks (MOFs) and metal exchange (ME) is introduced as a technique to install dispersed metal atoms into the mesoporous MOF, NU-1000. Zn-AIM, which contains four Zn atoms per Zr₆ node, has been synthesized through AIM and further characterized through density functional calculations to provide insight into the possible structure. Zn-AIM was then subjected to modification via transmetalation to yield uniform porous materials that present nonstructural Cu, Co, or Ni atoms. (Figure Presented).

Original language	English (US)
Pages (from-to)	1213-1219
Number of pages	7
Journal	Chemistry of Materials
Volume	28
Issue number	4
DOIs	https://doi.org/10.1021/acs.chemmater.5b04887
State	Published - Feb 23 2016

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© 2016 American Chemical Society.

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title = "Synthetic Access to Atomically Dispersed Metals in Metal-Organic Frameworks via a Combined Atomic-Layer-Deposition-in-MOF and Metal-Exchange Approach",

abstract = "The combination (AIM-ME) of atomic layer deposition in metal-organic frameworks (MOFs) and metal exchange (ME) is introduced as a technique to install dispersed metal atoms into the mesoporous MOF, NU-1000. Zn-AIM, which contains four Zn atoms per Zr6 node, has been synthesized through AIM and further characterized through density functional calculations to provide insight into the possible structure. Zn-AIM was then subjected to modification via transmetalation to yield uniform porous materials that present nonstructural Cu, Co, or Ni atoms. (Figure Presented).",

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AU - Truhlar, Donald G.

AU - Hupp, Joseph T.

AU - Farha, Omar K.

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AB - The combination (AIM-ME) of atomic layer deposition in metal-organic frameworks (MOFs) and metal exchange (ME) is introduced as a technique to install dispersed metal atoms into the mesoporous MOF, NU-1000. Zn-AIM, which contains four Zn atoms per Zr6 node, has been synthesized through AIM and further characterized through density functional calculations to provide insight into the possible structure. Zn-AIM was then subjected to modification via transmetalation to yield uniform porous materials that present nonstructural Cu, Co, or Ni atoms. (Figure Presented).

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Synthetic Access to Atomically Dispersed Metals in Metal-Organic Frameworks via a Combined Atomic-Layer-Deposition-in-MOF and Metal-Exchange Approach

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Energy Frontier Research Center For Inorganometallic Catalyst Design (DE-SC0012702)

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Synthetic Access to Atomically Dispersed Metals in Metal-Organic Frameworks via a Combined Atomic-Layer-Deposition-in-MOF and Metal-Exchange Approach

Abstract

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Energy Frontier Research Center For Inorganometallic Catalyst Design (DE-SC0012702)

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