Theoretical issues in electronic structure of the passivation layer

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Abstract

In this paper we review some fundamental concepts from the study of the physics of ordered oxides and of disordered metals. The passivation layer is a disordered oxide and thus requires mastery of both sets of concepts. We present some recent results on a model of highly disordered TiO2 which illustrates some of these ideas. In summary we discuss ways in which the possibility of metal-insulator transitions in the passivation layer can be further explored theoretically and experimentally.

Original languageEnglish (US)
Pages (from-to)213-223
Number of pages11
JournalCorrosion Science
Volume29
Issue number2-3
DOIs
StatePublished - 1989

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