Theoretical search for very short metal-actinide bonds: NUIr and isoelectronic systems

Laura Gagliardi; Pekka Pyykkö

doi:10.1002/anie.200353261

Theoretical search for very short metal-actinide bonds: NUIr and isoelectronic systems

Laura Gagliardi, Pekka Pyykkö

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

43 Scopus citations

Abstract

Cumulated triple bonds: A new class of molecules, the isoelectronic series of NUIr, (depicted) has been postulated and theoretically studied. The bond between the actinide and the 5d-metal atom is very short and is shown to correspond to triple bonding. The N-U bond is also a triple bond.

Original language	English (US)
Pages (from-to)	1573-1576
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	43
Issue number	12
DOIs	https://doi.org/10.1002/anie.200353261
State	Published - Mar 12 2004

Keywords

Computer chemistry
Density functional calculations
Iridium
Multiple bonding
Uranium

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Theoretical search for very short metal-actinide bonds: NUIr and isoelectronic systems

Abstract

Keywords

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