Vicinal dichlorine elimination at dichloroalkenes promoted by a well-defined iron(0) complex

Kristen A. Thoreson; Kristopher McNeill

doi:10.1039/c0dt01532f

Vicinal dichlorine elimination at dichloroalkenes promoted by a well-defined iron(0) complex

Kristen A. Thoreson, Kristopher McNeill

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Dechlorination reactions at sp² C-Cl bonds by a pentaphosphino zero-valent iron (ZVI) complex are proposed to follow an oxidative addition, β-Cl-elimination pathway en route to iron-chloride, iron-hydride and iron-acetylide products, the distribution being dependent on the nature of alkyne produced.

Original language	English (US)
Pages (from-to)	1646-1648
Number of pages	3
Journal	Dalton Transactions
Volume	40
Issue number	8
DOIs	https://doi.org/10.1039/c0dt01532f
State	Published - Feb 28 2011

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title = "Vicinal dichlorine elimination at dichloroalkenes promoted by a well-defined iron(0) complex",

abstract = "Dechlorination reactions at sp2 C-Cl bonds by a pentaphosphino zero-valent iron (ZVI) complex are proposed to follow an oxidative addition, β-Cl-elimination pathway en route to iron-chloride, iron-hydride and iron-acetylide products, the distribution being dependent on the nature of alkyne produced.",

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AU - Thoreson, Kristen A.

AU - McNeill, Kristopher

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N2 - Dechlorination reactions at sp2 C-Cl bonds by a pentaphosphino zero-valent iron (ZVI) complex are proposed to follow an oxidative addition, β-Cl-elimination pathway en route to iron-chloride, iron-hydride and iron-acetylide products, the distribution being dependent on the nature of alkyne produced.

AB - Dechlorination reactions at sp2 C-Cl bonds by a pentaphosphino zero-valent iron (ZVI) complex are proposed to follow an oxidative addition, β-Cl-elimination pathway en route to iron-chloride, iron-hydride and iron-acetylide products, the distribution being dependent on the nature of alkyne produced.

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Vicinal dichlorine elimination at dichloroalkenes promoted by a well-defined iron(0) complex

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