Deuterium Kinetic Isotope Effects and their Temperature Dependence in the Gas-Phase S_N2 Reactions X^–+ CH₃Y → CH₃X + Y^–(X, Y = Cl, Br, I)

Medicine & Life Sciences

• Deuterium 97%
• Isotopes 75%
• Gases 58%
• Kinetics 50%
• Temperature 50%
• Electrons 18%

Engineering & Materials Science

• Deuterium 100%
• Isotopes 85%
• Electron correlations 44%
• Gases 39%
• Rate constants 28%
• Temperature 27%
• Set theory 14%
• Experiments 8%

Chemical Compounds

• Kinetic Isotope Effect 76%
• Deuterium(.) 63%
• Transition State Theory 54%
• Electron Correlation 27%
• Transition State 19%
• Force 15%
• Rate Constant 15%